Pararosaniline
 | |
| Names | |
|---|---|
| IUPAC name
[4-[Bis(4-aminophenyl)methylidene]-1-cyclohexa-2,5-dienylidene]dianiline | |
| Other names
Pararosaniline p-rosaniline C.I. 42500 Para magenta | |
| Identifiers | |
569-61-9  | |
| 3D model (Jmol) | Interactive image |
| ChEBI | CHEBI:87663  |
| ChemSpider | 10819 |
| ECHA InfoCard | 100.008.475 |
| KEGG | C19210 |
| PubChem | 11293 |
| UNII | 20N4C0M8NM |
| |
| |
| Properties | |
| C19H17N3 | |
| Molar mass | 287.358 g/mol |
| Appearance | Green crystalline solid |
| Melting point | 268 to 270 °C (514 to 518 °F; 541 to 543 K) decomposes |
| Slightly soluble | |
| Hazards | |
| Safety data sheet | External MSDS |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| verify (what is ?) | |
| Infobox references | |
Pararosaniline, Basic Red 9, or C.I. 42500 is an organic compound with the formula [(H2NC6H4)3C]Cl. It is a magenta solid with a variety of uses as a dye.[1] It is one of the four components of basic fuchsine. (The others are rosaniline, new fuchsine and magenta II.)[2] It is structurally related to other triarylmethane dyes called methyl violets including crystal violet, which feature methyl groups on nitrogen.
It is prepared by the condensation of aniline and para-aminobenzaldehyde. Alternative it arises from the oxidation of 4,4'-bis(aminophenyl)methane in the presence of aniline.
Uses
- It is used to dye polyacrylonitrile fibers.
- Pararosaniline is used as a colorimetric test for aldehydes, in the Schiff test. It is the only basic fuchsine component suitable for making the aldehyde-fuchsine stain for pancreatic islet beta cells.[3]
- It has use as a Antischistosomal GB 908634 (1962 to Parke Davis & Co).
References
- ↑ Thomas Gessner and Udo Mayer "Triarylmethane and Diarylmethane Dyes" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim.doi:10.1002/14356007.a27_179
- ↑ Horobin RW, Kiernan JA (2002) Conn's Biological Stains, 10th ed. Oxford: BIOS.
- ↑ Mowry, RW; Emmel, VM (1978). "Aldehyde fuchsin staining, direct or after oxidation: problems and remedies, with special reference to pancreatic B cells, pituitaries and elastic fibers". Stain Technology. 53: 141–154. doi:10.3109/10520297809111457.
Further reading
- Colour Index 3rd Edition Volume 4 (PDF), Bradford: Society of Dyers and Colourists, 1971, p. 4388.
- Gessner, T.; Mayer, U. (2002), "Triarylmethane and Diarylmethane Dyes", Ullmann's Encyclopedia of Industrial Chemistry 6th Edition, Weinheim: Wiley-VCH, doi:10.1002/14356007.a27_179.
This article is issued from Wikipedia - version of the 7/11/2016. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.