Thallium(III) nitrate

Thallium(III) nitrate
Names
IUPAC name
thallium(3+) trinitrate
Identifiers
13746-98-0 N
3D model (Jmol) Interactive image
ChemSpider 140409 N
PubChem 159690
Properties
Tl(NO3)3
Molar mass 390.398
Appearance colorless solid
Melting point 103 °C (217 °F; 376 K)
Boiling point decomposes
decomposes
Hazards
Safety data sheet Mallinckrodt Baker
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Thallium(III) nitrate, also known as thallic nitrate, is a thallium compound with chemical formula Tl(NO3)3.[1] It is normally found as the trihydrate. It is a colorless and highly toxic solid. It is a strong oxidizing agent useful in organic synthesis. Among its many transformations, it oxidizes methoxyl phenols to quinone acetals, alkenes to acetals, and cyclic alkenes to ring-contracted aldehydes.[2]

References

  1. ↑ MSDS for thallium(III) nitrate
  2. ↑ Mukund P. Sibi, Luiz F. Silva Jr., Vânia M. T. Carneiro "Thallium(III) Nitrate Trihydrate" Encyclopedia of Reagents for Organic Synthesis 2008 John Wiley & Sons. doi:10.1002/047084289X.rt085.pub2
Salts and covalent derivatives of the Nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4− C N O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3 Co(NO3)2,
Co(NO3)3		 Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2		 Tl(NO3)3 Pb(NO3)2 Bi(NO3)3
BiO(NO3)		 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce(NO3)3,
Ce(NO3)4		 Pr Nd Pm Sm Eu Gd(NO3)3 Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr
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