Bromoiodomethane

Bromoiodomethane
Names


Preferred IUPAC name Bromo(iodo)methane
Other names Bromoiodomethane Bromomethyl iodide Iodobromomethane
Identifiers
CAS Number	557-68-6^Y
3D model (Jmol)	Interactive image
ChemSpider	61690^Y
ECHA InfoCard	100.156.567
PubChem	68407
InChI InChI=1S/CH2BrI/c2-1-3/h1H2^Y Key: TUDWMIUPYRKEFN-UHFFFAOYSA-N^Y
SMILES BrCI
Properties
Chemical formula	CH₂BrI
Molar mass	220.84 g·mol⁻¹
Appearance	Colourless liquid
Density	2.93 g mL⁻¹
Melting point	1 °C; 34 °F; 274 K
Boiling point	138 to 141 °C (280 to 286 °F; 411 to 414 K)
Refractive index (n_D)	1.6382
Hazards
GHS pictograms
GHS signal word	DANGER
GHS hazard statements	H315, H318, H335
GHS precautionary statements	P261, P280, P305+351+338
EU classification (DSD)	Xi
R-phrases	R37/38, R41
S-phrases	S26, S36/39
Related compounds
Related alkanes	Bromomethane Bromoethane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is ^YN ?)
Infobox references

Bromoiodomethane is a liquid mixed halomethane very soluble in chloroform.

Its critical point is at 367.85 °C and 6.3 MPa and refractive index is 1.6382 (20 °C, D).

References

Tarnovsky A. N.; Wall M.; Gustafsson M.; Lascoux N.; Sundström V.; Åkesson E. (March 2002). "Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation". J. Phys. Chem. A. 106 (25): 5999–6005(7). doi:10.1021/jp014306j. Retrieved 2007-06-29.
Liu Y.-J.; Ajitha D.; Krogh J. W.; Tarnovsky A. N.; Lindh R. (December 2005). "Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane". ChemPhysChem. 7 (4): 955–963(9). doi:10.1002/cphc.200500654. PMID 16596616. Retrieved 2007-06-29.
Zheng, X.; Phillips, D. L. (August 2000). "Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct". J. Chem. Phys. 113 (8): 3194–3203(10). Bibcode:2000JChPh.113.3194Z. doi:10.1063/1.1286920.
Liu K.; Zhao H.; Wang C.; Zhang A.; Ma S.; Li Z. (January 2005). "A theoretical study of bond selective photochemistry in CH₂BrI". J. Chem. Phys. 122 (4): 044310. Bibcode:2005JChPh.122d4310L. doi:10.1063/1.1835955. PMID 15740251. Retrieved 2007-06-29.

Halomethanes

Monosubstituted	CH₃F CH₃Cl CH₃Br CH₃I

Disubstituted	CH₂F₂ CH₂ClF CH₂BrF CH₂FI CH₂Cl₂ CH₂BrCl CH₂ClI CH₂Br₂ CH₂BrI CH₂I₂

Trisubstituted	CHF₃ CHClF₂ CHBrF₂ CHF₂I CHCl₂F CHBrClF CHClFI CHBr₂F CHBrFI CHFI₂ CHCl₃ CHBrCl₂ CHCl₂I CHBr₂Cl CHBrClI CHClI₂ CHBr₃ CHBr₂I CHBrI₂ CHI₃

Tetrasubstituted	CF₄ CClF₃ CBrF₃ CF₃I CCl₂F₂ CBrClF₂ CClF₂I CBr₂F₂ CBrF₂I CF₂I₂ CCl₃F CBrCl₂F CCl₂FI CBr₂ClF C*BrClFI CClFI₂ CBr₃F CBr₂FI CBrFI₂ CFI₃ CCl₄ CBrCl₃ CCl₃I CBr₂Cl₂ CBrCl₂I CCl₂I₂ CBr₃Cl CBr₂ClI CBrClI₂ CClI₃ CBr₄ CBr₃I CBr₂I₂ CBrI₃ CI₄

* Chiral compound.

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